Certain natural substances such as rubber and silk have useful plastic-like properties. But before the invention of plastic, only metal, clay and glass, all heavy and rigid, could be molded. Rubber has many of the properties of some plastics, but it loses its ability to retain its shape after repeated stretching or bending. Natural plastic-like materials are made up of long molecular chains called polymers that are formed of simple repeating units. The invention of plastic came from studying the chemistry of those polymer chains.